Bioplastics are gaining interest as an alternative to fossil-based plastics. In addition, biodegradable bioplastics may yield biogas after their use, giving an additional benefit. However, the biodegradability time in international norms (35 days) far exceeds processing times in anaerobic digestion facilities (21 days). As the bioplastic packaging does not indicate the actual biodegradability, it is important to understand the time required to biodegrade bioplastic if it ends up in the anaerobic digestion facility along with other organic waste. For this work, cellulose bioplastic film and polylactic acid (PLA) coffee capsules were digested anaerobically at 55 ℃ for 21 days and 35 days, which are the retention times for industrial digestors and as set by international norms, respectively. Different sizes of bioplastics were examined for this work. Bioplastic film produced more biogas than bioplastic coffee capsules. The biodegradability of bioplastic was calculated based on theoretical biogas production. With an increase in retention time, biogas production, as well as biodegradability of bioplastic, increased. The biodegradability was less than 50% at the end of 35 days for both bioplastics, suggesting that complete degradation was not achieved, and thus, the bioplastic would not be suitable for use in biogas digesters currently in use.
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Natural Deep Eutectic Solvents (NADES) represent a green chemistry alternative to utilization of common hazardous organic solvents. They were introduced by Abbott et al. [1], and were found to have a wide range of compositions and favorable properties. NADES are typically obtained by mixing hydrogen-bond acceptors (HBA), with hydrogen bond donors (HBD), leading to a significant depression of the melting point. The availability of components, simple preparation, biodegradability, safety, re usability and low cost are the significant advantages that call for research on their analytical applications. Three methods are most commonly used for preparing NADES: a) heating and stirring: the mixture until a clear liquid is formed; b) evaporating solvent from components solution with a rotatory evaporator; c) freeze drying of aqueous solutions.The common solvents for the extraction of anthocyanins are acidified mixtures of water with ethanol, methanol, or acetone. The anthocyanins extracts are susceptible to degradation due to high temperature, and the solvent properties (e.g. high pH) and the whole process can often be time-consuming. Extraction of anthocyanins from red cabbage by four NADES was investigated. It was demonstrated that NADES have comparable extraction efficiencies with conventional method with 0.1 M water solution of HCl. This indicates a possibility of utilization the Green chemistry extraction processes as a promising new green-extraction technology with low cost efficiency and environment friendly technology for production of safe food additives.
In the housing market enormous challenges exist for the retrofitting of existing housing in combination with the ambition to realize new environmentally friendly and affordable dwellings. Bio-based building materials offer the possibility to use renewable resources in building and construction. The efficient use of bio-based building materials is desirable due to several potential advantages related to environmental and economic aspects e.g. CO2 fixation and additional value. The potential biodegradability of biomaterials however demands also in-novative solutions to avoid e.g. the use of environmental harmful substances. It is essential to use balanced technological solutions, which consider aspects like service life or technical per-formance as well as environmental aspects. Circular economy and biodiversity also play an im-portant role in these concepts and potential production chains. Other questions arise considering the interaction with other large biomass users e.g. food production. What will be the impact if we use more bio-based building materials with regard to biodiversity and resource availability? Does this create opportunities or risks for the increasing use of bio-based building materials or does intelligent use of biomass in building materials offer the possibility to apply still unused (bio) resources and use them as a carbon sink? Potential routes of intelligent usage of biomass as well as potential risks and disadvantages are highlighted and discussed in relation to resource efficiency and decoupling concept(s).
Chemical preservation is an important process that prevents foods, personal care products, woods and household products, such as paints and coatings, from undesirable change or decomposition by microbial growth. To date, many different chemical preservatives are commercially available, but they are also associated with health threats and severe negative environmental impact. The demand for novel, safe, and green chemical preservatives is growing, and this process is further accelerated by the European Green Deal. It is expected that by the year of 2050 (or even as soon as 2035), all preservatives that do not meet the ‘safe-by-design’ and ‘biodegradability’ criteria are banned from production and use. To meet these European goals, there is a large need for the development of green, circular, and bio-degradable antimicrobial compounds that can serve as alternatives for the currently available biocidals/ preservatives. Anthocyanins, derived from fruits and flowers, meet these sustainability goals. Furthermore, preliminary research at the Hanze University of Applied Science has confirmed the antimicrobial efficacy of rose and tulip anthocyanin extracts against an array of microbial species. Therefore, these molecules have the potential to serve as novel, sustainable chemical preservatives. In the current project we develop a strategy consisting of fractionation and state-of-the-art characterization methods of individual anthocyanins and subsequent in vitro screening to identify anthocyanin-molecules with potent antimicrobial efficacy for application in paints, coatings and other products. To our knowledge this is the first attempt that combines in-depth chemical characterization of individual anthocyanins in relation to their antimicrobial efficacy. Once developed, this strategy will allow us to single out anthocyanin molecules with antimicrobial properties and give us insight in structure-activity relations of individual anthocyanins. Our approach is the first step towards the development of anthocyanin molecules as novel, circular and biodegradable non-toxic plant-based preservatives.
Plastic products are currently been critically reviewed due to the growing awareness on the related problems, such as the “plastic soup”. EU has introduced a ban for a number of single-use consumer products and fossil-based polymers coming in force in 2021. The list of banned products are expected to be extended, for example for single-use, non-compostable plastics in horticulture and agriculture. Therefore, it is crucial to develop sustainable, biodegradable alternatives. A significant amount of research has been performed on biobased polymers. However, plastics are made from a polymer mixed with other materials, additives, which are essential for the plastics production and performance. Development of biodegradable solutions for these additives is lacking, but is urgently needed. Biocarbon (Biochar), is a high-carbon, fine-grained residue that is produced through pyrolysis processes. This natural product is currently used to produce energy, but the recent research indicate that it has a great potential in enhancing biopolymer properties. The biocarbon-biopolymer composite could provide a much needed fully biodegradable solution. This would be especially interesting in agricultural and horticultural applications, since biocarbon has been found to be effective at retaining water and water-soluble nutrients and to increase micro-organism activity in soil. Biocarbon-biocomposite may also be used for other markets, where biodegradability is essential, including packaging and disposable consumer articles. The BioADD consortium consists of 9 industrial partners, a branch organization and 3 research partners. The partner companies form a complementary team, including biomass providers, pyrolysis technology manufacturers and companies producing products to the relevant markets of horticulture, agriculture and packaging. For each of the companies the successful result from the project will lead to concrete business opportunities. The support of Avans, University of Groningen and Eindhoven University of Technology is essential in developing the know-how and the first product development making the innovation possible.
The production, use, disposal and recovery of packaging not only generates massive volumes of waste, it also consumes raw materials, water and energy (Fitzpatrick et al. 2012). Simultaneously, consumers have shown an increasing interest in products incorporating sustainable and social attributes (Kletzan et al., 2006). As a result, environmentally friendly packaging, also called ecofriendly or sustainable packaging, has become mainstream. In this context, packaging is more than just ensuring the product's protection and easing transportation, it is also a communicative tool (Palmer, 2000) and it becomes associated with multiple drivers of the purchasing process. Consequently, companies face pressure to innovate responding to consumer demands, and focusing on sustainable solutions that reduce harmful materials and favour green alternatives for both, the product and the packaging. Although the above has triggered research on consumer choice for sustainable products and alternatives on sustainable packaging, the relation between sustainable packaging and consumer behaviour remains underexplored. This research unpacks this relationship, i.e., empirically verifies which dimensions (recyclability, biodegradability, reusability) of sustainable packaging are perceived and valued by consumers. Put differently, this research investigates consumer behaviour towards the functions of sustainable packaging in terms of product protection, convenience, reliability of information and promotion, and scrutinises the perceived credibility of the associated ethical responsibility claims. It aims to identify those packaging materials and/or sustainability characteristics perceived as more sustainable by consumers as well as the factors influencing actual consumer choice towards sustainable packaged products. We aim to gain more insights in the perceptual frame that different types of consumers apply when exposed to sustainable packaging. To this end, we will make use of revealed preference methods to measure consumer valuations of sustainable packaged products. This game-theoretic approach should provide a more complete depiction of consumers' perceptions and preferences.
