Thermal batteries, which store and release energy by hydrating and dehydrating salt crystals, hold great promise for domestic heating. Such batteries can be charged from waste heat from industrial processes, and discharged to provide neighbourhood heating. Unlike hot water storage systems, the energy is stored at room temperature, so the thermal losses are very low, making a salt battery highly efficient. However, the electrochemical change of the salt due to hydration and dehydration is very small, making it difficult to measure how much energy is stored in a battery.
One promising technique is to measure the absolute humidity of the inlet and outlet air flow. The difference in humidity, combined with a rate equation model allows the total mass of water stored in the battery to be calculated, which can then be used to calculate the energy storage and battery power flow.
However, there are several uncertainties in this approach. Commercially available sensors age over time, sometimes quite suddenly. It is not yet known if software can be used to compensate for sensor aging, or if a different sensor type is required. In addition to aging, each measurement is subject to random noise, which will be integrated into the model used to calculate the charge of the battery. It is not yet known how the noise will influence charge estimates.
On the other hand, the sensor system must be as durable as domestic heating systems (decades). Hence, it is required to understand sensor aging in order to validate the sensor system for its intended use.
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