Within the Flexnode Plus project the long-term degradation characteristics of a proton exchange membrane (PEM) electrolyzer (5.5 kW, AC, 1 Nm3/h H2) and fuel cell (1.0 kW, DC, 0.9 Nm3/h) was experimentally tested. The electrolyzer unit was operated at various loads and pressures for approximately 750 hours in total, while the fuel cell was operated at a constant load of 1 Ω resistance for approximately 1120 hours in total. The efficiency of the hydrogen production in the electrolyzer and the electricity production in the fuel cell was expressed using the hourly average system efficiency and average cell efficiency. Inorder to predict the state of health and remaining lifetime of the electrolyzer cell and fuel cell, the decay of the cell voltage over time was monitored and the direct mapping from aging data method was used.The electrolyzer cell showed a stable cell voltage and cell efficiency in the studied time period, with an average cell voltage decay rate of 0.5 μV/h. The average cell voltage of the fuel cell dropped with a rate of 2 μV/h during the studied time period.
Wind and solar power generation will continue to grow in the energy supply of the future, but its inherent variability (intermittency) requires appropriate energy systems for storing and using power. Storage of possibly temporary excess of power as methane from hydrogen gas and carbon dioxide is a promising option. With electrolysis hydrogen gas can be generated from (renewable) power. The combination of such hydrogen with carbon dioxide results in the energy carrier methane that can be handled well and may may serve as carbon feedstock of the future. Biogas from biomass delivers both methane and carbon dioxide. Anaerobic microorganisms can make additional methane from hydrogen and carbon dioxide in a biomethanation process that compares favourably with its chemical counterpart. Biomethanation for renewable power storage and use makes appropriate use of the existing infrastructure and knowledge base for natural gas. Addition of hydrogen to a dedicated biogas reactor after fermentation optimizes the biomethanation conditions and gives maximum flexibility. The low water solubility of hydrogen gas limits the methane production rate. The use of hollow fibers, nano-bubbles or better-tailored methane-forming microorganisms may overcome this bottleneck. Analyses of patent applications on biomethanation suggest a lot of freedom to operate. Assessment of biomethanation for economic feasibility and environmental value is extremely challenging and will require future data and experiences. Currently biomethanation is not yet economically feasible, but this may be different in the energy systems of the near future.
In the course of the “energie transitie” hydrogen is likely to become a very important energy carrier. The production of hydrogen (and oxygen) by water electrolysis using electricity from sun or wind is the only sustainable option. Water electrolysis is a well-developed technique, however the production costs of hydrogen by electrolysis are still more expensive than the conventional (not sustainable) production by steam reforming. One challenge towards the large scale application of water electrolysis is the fabrication of stable and cheap (noble metal free) electrodes. In this project we propose to develop fabrication methods for working electrodes and membrane electrode stack (MEAs) that can be used to implement new (noble metal free) electrocatalysts in water electrolysers.
