BACKGROUND: Sour cherry (Prunus cerasus L.) stones are the major byproduct of the cherry industry and the efficient management of this biowaste can lead to achieving the food processing sustainability aimed at by the modern food industry. Despite its significant content of lipids, the valorization of cherry stone waste as feedstock for lipid extraction appears to be limited due to the high moisture content. This study explores the primary factors that affect the yield of lipid extraction using Soxhlet, Randall and supercritical carbon dioxide (scCO2) extraction methods, with a particular emphasis on yield optimization for green extraction technologies (scCO2). RESULTS: The investigation revealed an increased lipid extraction yield for scCO2 from 7.4 for dry crushed stones to 20.6 g per 100 g dry weight when the cherry kernels are separated. The high initial moisture content affected all three extraction methods, but mostly impacted the scCO2 extraction, resulting in the co-extraction of an aqueous phase. Lipid and aqueous yield could be manipulated by time, temperature and pressure. However, no observable influence on the composition of fatty acid methyl esters was detected. CONCLUSION: Numerous approaches are shown to enhance the lipid yield from cherry stone waste, depending on the desired outcome. When dealing with wet samples, Randall extraction proves to be the most effective method. On the other hand, scCO2 extraction presents distinct advantages, such as the extraction of food-grade lipids and the co-extraction of a unique aqueous phase, which comes at the expense of a reduced lipid yield. © 2024 The Authors. Journal of Chemical Technology and Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry (SCI).
Fish and vegetable protein sources are relatively underutilized for human consumption in comparison to meat, dairy and egg protein sources. Only part of the available fish proteins is used: fish is to small for human consumption and fish has a high proportion of by-products, up to 50% of fish weight is not used. This project aims to develop products and processes for creating healthy high valued consumer products based upon vegetable proteins and fish/crustacean proteins from by-products or from neglected fish. Three innovative processes are developed:1) Iso-electric solubilization and precipitation of fish/crustacean proteins from by-products,2) Networked vegetable/fish protein textures based upon low moisture extrusion processes3) Fibrous vegetable/fish protein textures produced with high moisture extrusion processes.Two innovative processes are applied:1) Food products with water-oil-water emulsions with isolated fish proteins2) Food products with sous-vide prepared fish fillets in semi industrial context.Different consumer product prototypes will be developed like fish nuggets, fish flakes and fish crackers.The Nuprotex project created successfully two new processes. Hanzehogeschool developed the process for fish protein isolation based upon iso electric solubilization and precipitation. With this process it was possible to recover about 15% weight of additional proteins from fish by-products. Please be aware that the yield of fish fillets from the fish is only about 30% of fish weight. So this is an important increase in food grade proteins! These Isolated Fish Proteins are successfully converted into several consumer prototype products like multiple emulsions for savory liquid products and fish cake/cracker applications. A sous-vide cooking process for fish fillets was developed with respect to microbial safety. It was shown that a microbial safe route could be developed, however further research is necessary to confirm these preliminary results.DIL has developed successfully an high moisture extrusion process for isolated fish proteins, grinded fish by products and vegetable proteins. This semi-finished product is successfully applied by for developing deep fried fish nuggets and fish burgers. DIL produced fish pellets which are suitable for applications as fish feed as is demonstrated in actual trials. Further research must demonstrate the quality of the feed product in actual growth experiments with fish.This project has clearly demonstrated that it is possible to produce with fish by-products added value consumer products. A possible increase of food-grade fish protein of about 15% on fresh weight base of processed fish is possible.
This study introduces a detailed method for analyzing the buckling behavior of laminated composite structures strengthened with multi-walled carbon nanotubes (MWCNTs). We propose a multi-scale analysis that combines analytical and computational techniques to assess the mechanical performance of MWCNT-reinforced composites under combined moisture, temperature, and mechanical stress conditions. The Halpin-Tsai equations are used to calculate the overall stiffness properties of the nano-enhanced matrix, considering factors like MWCNT clustering, alignment, and curvature. Additionally, we incorporate the nanoscopic, size-dependent features of MWCNTs into our model. The Chamis micromechanical formulas are applied to determine the individual elastic properties of the nanocomposite layers, considering the impacts of temperature and moisture. We then explore how variables such as MWCNT content and size, along with temperature and moisture levels, influence the critical buckling load of MWCNT-based laminated composite beams and plates using our multi-scale model. Our results are successfully compared with existing experimental and theoretical data to validate our approach. The developed method offers significant insights for the design and optimization of MWCNT-reinforced composites, potentially benefiting various engineering fields, including aerospace and automotive industries.
Recent research by the renowned Royal Institution of Chartered Surveyors (RICS) shows that more than 2/3 of all CO2 is emitted during the building process and less than 1/3 during use to heat the building and the tap water. Lightweight, local and biobased materials such as biocomposites to replace concrete and fossil based cladding are in the framework of climate change, a necessity for future building. Using plant fiber in polymer composites is especially interesting for construction since natural fibers exhibit comparative good mechanical properties with small specific weight, which defines the potential for lightweight constructions. The use of renewable resources, will affect the ecosystem favorably and the production costs of construction materials could also decrease. However, one disadvantage of natural fibers in plastics is their hydrophilic properties. In construction the materials need to meet special requirements like the resistance against fluctuating weather conditions (Ticoalu et al., 2010). In contrast to synthetic fibers, the natural ones are more moisture- and UV-radiation-sensitive. That may lead to degradation of these materials and a decreasing in quality of products. (Lopez et al., 2006; Mokhothu und John, 2017) Tanatex and NPSP have approached CoE BBE/Avans to assist in a study where fibres impregnated with the (modified) Tanatex products will be used for reinforcement of thermoset biopolymers. The influence of the different Tanatex products on the moisture absorption of natural/cellulosic fibers and the adhesion on the fibers on main composite matrix will be measured. The effect of Tantex products can optimize the bonding reaction between the resin and the fibers in the (bio) composite and result to improved strength and physico-chemical properties of the biocomposite materials. (word count: 270)
In the past, textile material was used to add value to buildings in various applications, as well as improving building performance in terms or in terms of building and acoustics properties, and increasing the esthetic value.Textiles are light in weight, easy to shape, strong, insulating, moisture-regulating and can be provided with extra functions. Particularly in areas with an earthquake risk, as well as cases with a temporary demand for flexible shelters, textiles and primary use.
Buildings are responsible for approximately 40% of energy consumption and 36% of carbon dioxide (CO2) emissions in the EU, and the largest energy consumer in Europe (https://ec.europa.eu/energy). Recent research shows that more than 2/3 of all CO2 is emitted during the building process whereas less than 1/3 is emitted during use. Cement is the source of about 8% of the world's CO2 emissions and innovation to create a distributive change in building practices is urgently needed, according to Chatham House report (Lehne et al 2018). Therefore new sustainable materials must be developed to replace concrete and fossil based building materials. Lightweight biobased biocomposites are good candidates for claddings and many other non-bearing building structures. Biocarbon, also commonly known as Biochar, is a high-carbon, fine-grained solid that is produced through pyrolysis processes and currently mainly used for energy. Recently biocarbon has also gained attention for its potential value with in industrial applications such as composites (Giorcellia et al, 2018; Piri et.al, 2018). Addition of biocarbon in the biocomposites is likely to increase the UV-resistance and fire resistance of the materials and decrease hydrophilic nature of composites. Using biocarbon in polymer composites is also interesting because of its relatively low specific weight that will result to lighter composite materials. In this Building Light project the SMEs Torrgas and NPSP will collaborate with and Avans/CoE BBE in a feasibility study on the use of biocarbon in a NPSP biocomposite. The physicochemical properties and moisture absorption of the composites with biocarbon filler will be compared to the biocomposite obtained with the currently used calcium carbonate filler. These novel biocarbon-biocomposites are anticipated to have higher stability and lighter weight, hence resulting to a new, exciting building materials that will create new business opportunities for both of the SME partners.
